Aromatic chloroosmacyclopentatrienes
Zhenwei Chu1, Guomei He1, Chuan Shi2
1Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005, China.
Abstract:
Aromatic metallacycles are of considerable current interest. Reported aromatic metallacycles are mainly those with carbon, nitrogen, oxygen and sulfur. In this work, we report the synthesis and characterization of aromatic chloroosmacyclopentatrienes, which represent the first structurally confirmed metallaaromatic with a chlorine atom in its framework. Single-crystal X-ray diffraction studies show that these planar chloroosmacyclopentatrienes possess a very short Os-ClC distance suggesting M=ClC bond character.
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