Biochar-supported sulfurized nanoscale zero-valent iron facilitates extensive dechlorination and rapid removal of...

Nanoscale zero-valent iron (NZVI) has been widely used in rapid remediation of contaminants. However, several obstacles such as aggregation and surface passivation hampered NZVI from further application. In this study, sulfurized nanoscale-zero valent iron supported by biochar (BC-SNZVI) was successfully synthesized and utilized for highly efficient 2,4,6-trichlorophenol (2,4,6-TCP) dechlorination in aqueous solution. SEM-EDS analysis revealed the even distribution of SNZVI on the surface of BC. FTIR, XRD, XPS and N₂ Brunauer-Emmett-Teller (BET) adsorption analyses were carried out to characterize the materials. Results showed that BC-SNZVI with S/Fe molar ratio of 0.088, Na₂S₂O₃ as sulfurization agent, and pre-sulfurization as the sulfurization strategy exhibited the superior performance for 2,4,6-TCP removal. The overall removal of 2,4,6-TCP was well described with the pseudo-first-order kinetics (R² > 0.9), and the observed kinetics constant K_obs was 0.083 min^-1 with BC-SNZVI, which was one order of magnitude higher than that of BC-NZVI (0.0092 min^-1) and SNZVI (0.0042 min^-1), and two orders of magnitude higher than that of NZVI (0.00092 min^-1). Moreover, the removal efficiency of 2,4,6-TCP reached 99.5% by BC-SNZVI with dosage of 0.5 g L^-1, initial 2,4,6-TCP concentration of 30 mg L^-1 and initial solution pH of 3.0 within 180 min. The removal of 2,4,6-TCP by BC-SNZVI was acid-promoted and the removal efficiencies of 2,4,6-TCP decreased with the increase of initial 2,4,6-TCP concentrations. Furthermore, more extensive dechlorination of 2,4,6-TCP was achieved with BC-SNZVI and complete dechlorination product phenol became predominant. The facilitation of sulfur for Fe⁰ utilization and electron distribution in the presence of biochar remarkably enhanced the dechlorination performance of BC-SNZVI for 2,4,6-TCP. These findings provide insights into BC-SNZVI as an alternative engineering carbon based NZVI material for treating chlorinated phenols.