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Updated: Jul 30, 2025
Morphology Control for Fully Printable Organic–Inorganic Bulk-heterojunction Solar Cells Based on a Ti-alkoxide and Semiconducting Polymer
Published on: January 10, 2017
The solvent effect on the morphology and molecular ordering of benzothiadiazole-based small molecule for
Cuc Kim Trinh1,2, Ha Som Oh3, Hanleem Lee3,4
1Chemical Engineering in Advanced Materials and Renewable Energy Research Group, School of Technology, Van Lang University Ho Chi Minh City Vietnam cuc.tk@vlu.edu.vn.
Abstract:
A small molecule organic semiconductor, D(D'-A-D')2 comprising benzothiadiazole as an acceptor, 3-hexylthiophene, and thiophene as donors, was successfully synthesized. X-ray diffraction and atomic force microscopy were used to investigate the effect of a dual solvent system with varying ratios of chloroform and toluene on film crystallinity and film morphology via inkjet printing. The film prepared with a chloroform to toluene ratio of 1.5 : 1 showed better performance with improved crystallinity and morphology due to having enough time to control the arrangement of molecules. In addition, by optimizing ratios of CHCl3 to toluene, the inkjet-printed TFT based on 3HTBTT using a CHCl3 and toluene ratio of 1.5 : 1 was successfully fabricated and exhibited a hole mobility of 0.01 cm2 V-1 s-1 due to the improved molecular ordering of the 3HTBTT film.
