Light Control-Induced Oxygen Vacancy Generation and In Situ Surface Heterojunction Reconstruction for Boosting CO₂...

The weak adsorption of CO₂ and the fast recombination of photogenerated charges harshly restrain the photocatalytic CO₂ reduction efficiency. The simultaneous catalyst design with strong CO₂ capture ability and fast charge separation efficiency is challenging. Herein, taking advantage of the metastable characteristic of oxygen vacancy, amorphous defect Bi₂O₂CO₃ (named BO_vC) was built on the surface of defect-rich BiOBr (named BO_vB) through an in situ surface reconstruction progress, in which the CO₃^2- in solution reacted with the generated Bi^(3-x)+ around the oxygen vacancies. The in situ formed BO_vC is tightly in contact with the BO_vB and can prevent the further destruction of the oxygen vacancy sites essential for CO₂ adsorption and visible light utilization. Additionally, the superficial BO_vC associated with the internal BO_vB forms a typical heterojunction promoting the interface carriers' separation. Finally, the in situ formation of BO_vC boosted the BOvB and showed better activity in the photocatalytic reduction of CO₂ into CO (three times compared to that of pristine BiOBr). This work provides a comprehensive solution for governing defects chemistry and heterojunction design, as well as gives an in-depth understanding of the function of vacancies in CO₂ reduction.