In Situ Spectroscopic Studies of NH₃ Oxidation of Fe-Oxide/Al₂O₃

Simple temperature-regulated chemical vapor deposition was used to disperse iron oxide nanoparticles on porous Al₂O₃ to create an Fe-oxide/Al₂O₃ structure for catalytic NH₃ oxidation. The Fe-oxide/Al₂O₃ achieved nearly 100% removal of NH₃, with N₂ as a major reaction product at temperatures above 400 °C and negligible NO emissions at all experimental temperatures. The results of a combination of in situ diffuse reflectance infrared Fourier-transform spectroscopy and near-ambient pressure-near-edge X-ray absorption fine structure spectroscopy suggest a N₂H₄-mediated oxidation mechanism of NH₃ to N₂ via the Mars-van Krevelen pathway on the Fe-oxide/Al₂O₃ surface. As a catalytic adsorbent-an energy-efficient approach to reducing NH₃ levels in living environments via adsorption and thermal treatment of NH₃-no harmful NO emissions were produced during the thermal treatment of the NH₃-adsorbed Fe-oxide/Al₂O₃ surface, while NH₃ molecularly desorbed from the surface. A system with dual catalytic filters of Fe-oxide/Al₂O₃ was designed to fully oxidize this desorbed NH₃ to N₂ in a clean and energy-efficient manner.