Is chemical analysis suitable for detecting mycotoxins in agricultural commodities and foodstuffs?

The assessment of the risks of mycotoxins to humans through consuming contaminated foods resulted in specific legislation that evaluates the presence, quantities, and type of mycotoxins in agricultural commodities and foodstuffs. Thus, to ensure compliance with legislation, food safety and consumer health, the development of suitable analytical procedures for identifying and quantifying mycotoxins in the free or modified form, in low-concentration and in complex samples is necessary. This review reports the application of the modern chemical methods of analysis employed in mycotoxin detection in agricultural commodities and foodstuffs. It is reported extraction methods with reasonable accuracy and those present characteristics according to guidelines of Green Analytical Chemistry. Recent trends in mycotoxins detection using analytical techniques are presented and discussed, evaluating the robustness, precision, accuracy, sensitivity, and selectivity in the detection of different classes of mycotoxins. Sensitivity coming from modern chromatographic techniques allows the detection of very low concentrations of mycotoxins in complex samples. However, it is essential the development of more green, fast and more suitable accuracy extraction methods for mycotoxins, which agricultural commodities producers could use. Despite the high number of research reporting the use of chemically modified voltammetric sensors, mycotoxins detection still has limitations due to the low selectivity from similar chemical structures of mycotoxins. Furthermore, spectroscopic techniques are rarely employed due to the limited number of reference standards for calibration procedures.