New Network Polymer Electrolytes Based on Ionic Liquid and SiO₂ Nanoparticles for Energy Storage Systems

Elementary processes of electro mass transfer in the nanocomposite polymer electrolyte system by pulse field gradient, spin echo NMR spectroscopy and the high-resolution NMR method together with electrochemical impedance spectroscopy are examined. The new nanocomposite polymer gel electrolytes consisted of polyethylene glycol diacrylate (PEGDA), salt LiBF₄ and 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF₄) and SiO₂ nanoparticles. Kinetics of the PEGDA matrix formation was studied by isothermal calorimetry. The flexible polymer-ionic liquid films were studied by IRFT spectroscopy, differential scanning calorimetry and temperature gravimetric analysis. The total conductivity in these systems was about 10^-4 S cm^-1 (-40 °C), 10^-3 S cm^-1 (25 °C) and 10^-2 S cm^-1 (100 °C). The method of quantum-chemical modeling of the interaction of SiO₂ nanoparticles with ions showed the advantage of the mixed adsorption process, in which a negatively charged surface layer is formed from Li⁺ BF₄^- ions on silicon dioxide particles and then from ions of the ionic liquid EMI⁺ BF₄^-. These electrolytes are promising for use both in lithium power sources and in supercapacitors. The paper shows preliminary tests of a lithium cell with an organic electrode based on a pentaazapentacene derivative for 110 charge-discharge cycles.