Open-framework hybrid zinc/tin selenide as an ultrafast adsorbent for Cs⁺, Ba²⁺, Co²⁺, and Ni²

Efficient adsorption of radioactive ¹³⁷Cs⁺ and ⁶⁰Co²⁺ and their decay products ¹³⁷Ba²⁺ and ⁶⁰Ni²⁺ bears significance for hazard elimination in case of nuclear emergency, which relies on the adsorption rate enhancement that takes advantages of compositional and structural optimization. Herein, we report a zinc-doped selenidostannate constructed from T2-supertetrahedral clusters, namely K_3.4(CH₃NH₃)_0.45(NH₄)_0.15Zn₂Sn₃Se₁₀·3.4 H₂O (ZnSnSe-1K). The soft Se and micro-porosity synergistically endow this material with a binding affinity to Cs⁺, Ba²⁺, Co²⁺, and Ni²⁺ ions and ultrafast kinetics with R > 97.6% in 2-60 min. In particular, ZnSnSe-1K can remove 99.34% of Cs⁺ in 2 min ⁽K_d^Cs > 1.5 × 10⁵ mL g^-1), contributing to a record rate constant k₂ of 9.240 g mg^-1 min^-1 that surpasses all metal chalcogenide adsorbents. ZnSnSe-1K exhibits good acid/base tolerance (pH = 0-12), and the adsorption capacities at neutral are 253.61 ± 9.15, 108.94 ± 25.32, 45.76 ± 14.19 and 38.49 ± 2.99 mg g^-1 for Cs⁺, Ba²⁺, Co²⁺, and Ni²⁺, respectively. The adsorption performances resist well co-existing cations and anions, and the removal rates can keep above or close to 90% even in sea water. ZnSnSe-1K is employed in continuous column and membrane filtration, both of which shows excellent elimination efficiency (R > 99%) for mixed Cs⁺, Ba²⁺, Co²⁺, and Ni²⁺. Especially, the membrane with an ultrathin (70 µm) ZnSnSe-1K layer can remove 97-100% Cs⁺ in suction filtration with a short contact time of 0.33 s. Combined with the simple synthesis, facile elution and great irradiation resistance, ZnSnSe-1K emerges as a selenide adsorbent candidate for use in environmental remediation especially that involving nuclear waste disposal.