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Updated: Jul 20, 2025

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
Introducing proton/electron mediators enhances the catalytic ability of an iron porphyrin complex for photochemical
Maho Imai1, Kento Kosugi1, Yutaka Saga1,2
1Division of Applied Chemistry, Graduate School of Engineering Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan. mio@chem.eng.osaka-u.ac.jp.
Abstract:
A novel iron porphyrin complex with hydroquinone moieties as proton/electron mediators at meso positions was designed and synthesised. The complex serves as an efficient catalyst for photochemical CO2 reduction, and its turnover frequency (TOF = 1.3 × 104 h-1) was the highest among those of comparable systems with sufficient durability.
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