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(NH4)2[UO2Cl4]·2H2O, a new uranyl tetra-chloride with ammonium charge-balancing cations
Tsuyoshi A Kohlgruber1, Robert G Surbella Iii1
1Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, WA, 99354, USA.
Abstract:
A new uranyl tetra-chloride salt with chemical formula, (NH4)2[UO2Cl4]·2H2O, namely, di-ammonium uranyl tetra-chloride dihydrate, 1, was prepared and crystallized via slow evaporation from a solution of 2 M hydro-chloric acid. As confirmed by powder X-ray diffraction, the title compound crystallizes with an ammonium chloride impurity that formed as a result of the breakdown of a triazine precursor. The (UO2Cl4)2- dianion is charge balanced by ammonium cations, while an extensive hydrogen-bond network donated from structural water mol-ecules stabilize the overall assembly. Compound 1 adds to the extensive collection of actinyl tetra-chloride salts, but it represents the first without an alkali cation for purely inorganic compounds. Diffuse reflectance and luminescence spectra show typical absorption and emission behavior, respectively, of uranyl materials.
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