AirQuality Lab-on-a-Drone: A Low-Cost 3D-Printed Analytical IoT Platform for Vertical Monitoring of Gaseous H₂S

The measurement of gaseous compounds in the atmosphere is a multichallenging task due to their low concentration range, long and latitudinal concentration variations, and the presence of sample interferents. Herein, we present a quadcopter drone deployed with a fully integrated 3D-printed analytical laboratory for H₂S monitoring. Also, the analytical system makes part of the Internet of Things approach. The analytical method applied was based on the reaction between fluorescein mercuric acetate and H₂S that led to fluorescence quenching. A 5 V micropump at a constant airflow of 50 mL min^-1 was employed to deliver constant air into a flask containing 800 μL of the reagent. The analytical signal was obtained using a light-emitting diode and a miniaturized digital light detector. The method enabled the detection of H₂S in the range from 15 to 200 ppbv, with a reproducibility of 5% for a sampling time of 10 min and an limit of detection of 9 ppbv. All devices were controlled using an Arduino powered by a small power bank, and the results were transmitted to a smartphone via Bluetooth. The proposed device resulted in a weight of 300 g and an overall cost of ∼50 USD. The platform was used to monitor the concentration of H₂S in different intervals next to a wastewater treatment plant at ground and vertical levels. The ability to perform all analytical steps in the same device, the low-energy requirements, the low weight, and the attachment of data transmission modules offer new possibilities for drone-based analytical systems for air pollution monitoring.