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Updated: Jul 12, 2025

07:03
Low-energy Cathodoluminescence for OxyNitride Phosphors
Published on: November 15, 2016
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Eu3+ doped ZnAl layered double hydroxides as calibrationless, fluorescent sensors for carbonate
Alysson F Morais1,2,3, Ivan G N Silva1, Bruno J Ferreira1
1Instituto de Física da Universidade de São Paulo, 05508-090 - São Paulo, SP, Brazil. dmustafa@if.usp.br.
Abstract:
The photoluminescence properties (PL) of Eu3+ hosted in the hydroxide layers of layered double hydroxides (LDHs) enables calibrationless quantification of anions in the interlayers. The concept is demonstrated during the nitrate-to-carbonate ion exchange in Zn2+/Al3+/Eu3+ LDHs and can be implemented as a remote optical sensor to detect intrusion of anions such as Cl- or CO32-.

