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Updated: Jul 11, 2025
Ohmic Contact Fabrication Using a Focused-ion Beam Technique and Electrical Characterization for Layer Semiconductor Nanostructures
Published on: December 5, 2015
Optoelectronic properties of octahedral molybdenum cluster-based materials at a single crystal level
Elena Segura-Sanchis1, Ana Moreno1, Fernando Ramiro-Manzano1
1Instituto de Tecnología Química, Universitat Politècnica de València - Consejo Superior de Investigaciones Científicas (UPV-CSIC), Avd. de los Naranjos s/n, 46022 Valencia, Spain. mfeliz@itq.upv.es.
Abstract:
Octahedral molybdenum (Mo6) clusters constitute suitable building blocks for the design of promising single crystal materials in the field of optoelectronics. Here, we prepared single crystals composed of hydroxo Mo6X8 (X = Br, Cl) cluster complexes interconnected by H-bonding interactions with water molecules and protons. The optoelectronic responses and the absorption and emission spectra of these cluster-based single crystals were acquired upon light irradiation, and they show dependency on the nature of the halogens, with the brominated cluster being the most conductive. A fast photoelectrical response was recorded and it showed remarkable stability after multiple illumination on/off cycles. The results obtained provide relevant information for the development of photonic and optoelectronic devices, sensors and photocatalysts.
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