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Chemical Chartographisis: a contemporary perspective in molecular design and synthesis
1Department of Chemistry, School of Life Sciences, University of Sussex, Brighton, BN1 9QJ, UK. G.Kostakis@sussex.ac.uk.
Abstract:
The use of flexible molecular systems in solution, without strictly controlling their behaviour, has frequently been productive. Their potential could increase by a more holistic view of the reaction(s) process(es) in which they are involved. In this perspective, we introduce a broader approach - "Chemical Chartographisis" - and discuss three projects in detail to illustrate its potential. The topics involve bimetallic 3d/4f species and coordination compounds built from benzotriazole-based and (a)symmetric salan ligands and focus on catalytic and, in less detail, biological-related examples.
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