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Updated: Jul 9, 2025
Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
Eosin Y-Based Metal-Organic Framework Synergistic with Cobalt(II) Complex for Hydrogen Evolution through Photoinduced
Hao Zheng1, Li Pei1, Jianguo Bai1
1Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou, Jiangsu 221116, P. R. China.
Abstract:
Photocatalytic hydrogen evolution reaction (HER) is a promising approach for producing clean energy and has the potential to play an important role in the transition toward a more sustainable and environmentally friendly energy system. Optimizing the photoinduced electron transfer (PET) process and increasing visible-light utilization play a central role in photocatalysis. Herein, we built a novel Eosin Y-based metal-organic framework (Zn-EYTP) by synergizing a cobalt(II) complex for boosting the H2 evolution efficiency through photoinduced intermolecular electron transfer. Under optimized conditions, the maximum H2 evolution efficiency for Zn-EYTP was determined to be a turnover number (TON) value of 11,100 under green LED irradiation. And the synthesized Zn-EYTP photocatalysts could be easily recycled to restore the initial photocatalytic activity even after 3 cycles. Detailed studies reveal that the significantly enhanced HER activity in Zn-EYTP could be ascribed to the effective separation of photogenerated charges and the synergistic intermolecular interaction between Zn-EYTP and [Co(bpy)3]Cl2. The present work enables a deeper understanding of the importance of the PET process for enhanced HER photocatalytic activities, which will provide a viable strategy for the development of highly efficient photocatalysts.
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