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Indicators02:39

Indicators

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Certain organic substances change color in dilute solution when the hydronium ion concentration reaches a particular value. For example, phenolphthalein is a colorless substance in any aqueous solution with a hydronium ion concentration greater than 5.0 × 10−9 M (pH < 8.3). In more basic solutions where the hydronium ion concentration is less than 5.0 × 10−9 M (pH > 8.3), it is red or pink. Substances such as phenolphthalein, which can be used to determine the pH of a solution, are...
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Manufacturing of a Nafion-coated, Reduced Graphene Oxide/Polyaniline Chemiresistive Sensor to Monitor pH in Real-time During Microbial Fermentation
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Low-Cost Optical pH Sensor with a Polyaniline (PANI)-Sensitive Layer Based on Commercial Off-the-Shelf (COTS)

Serguei Stoukatch1, Marc Debliquy2, Francois Dupont1

  • 1Microsys Laboratory, Department of Electrical Engineering and Computer Science (Montefiore Institute), University of Liège, 4000 Liège, Belgium.

Micromachines
|December 23, 2023
PubMed
Summary

We developed a low-cost, compact pH sensor using a polyaniline (PANI) thin film. This simple, functional device offers broad pH range sensitivity and requires minimal sample volume, making it ideal for various applications.

Keywords:
COTS componentscolorimetric characterizationoptical pH sensoroptical sensorpolyaniline

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Area of Science:

  • Materials Science
  • Analytical Chemistry
  • Sensor Technology

Background:

  • Polyaniline (PANI) is a conductive polymer with potential for chemical sensing.
  • Existing PANI-based pH sensors often rely on complex and expensive excitation or detection methods.
  • There is a need for cost-effective, simple, and robust pH sensing solutions.

Purpose of the Study:

  • To present a novel, low-cost, and compact prototype pH sensor.
  • To demonstrate a simple and efficient PANI deposition technique.
  • To validate the sensor's performance across a wide pH range.

Main Methods:

  • Fabrication of a PANI thin film via a low-cost liquid-phase deposition process.
  • Integration of a red-light-emitting diode (LED) and photodiode (PD) for optical detection.
  • Development of integrated packaging using commercial off-the-shelf (COTS) components and surface mounting technology (SMT).

Main Results:

  • The PANI layer exhibited excellent stability, solvent resistance, and compatibility.
  • The sensor demonstrated sensitivity in the broad pH range of 3 to 9.
  • The device requires a minimal sample volume of 55 µL and uses simple optical components.

Conclusions:

  • A fully functional, low-cost pH sensor prototype was successfully developed.
  • The sensor's design avoids sophisticated and expensive techniques, enhancing its practicality.
  • The developed sensor is suitable for numerous applications requiring reliable pH monitoring.