Enhancing the Performance of Wide-Bandgap Polymer-Based Organic Solar Cells through Silver Nanorod Integration

Light trapping induced by the introduction of metallic nanoparticles has been shown to improve photo absorption in organic solar cells (OSCs). Researchers in the fields of plasmonics and organic photovoltaics work together to boost sunlight absorption and photon-electron interactions in order to improve device performance. In this contribution, an inverted OSC was fabricated by using indacenodithieno[3,2-b]thiophene-alt-2,2'-bithiazole (PIDTT-BTz) as a wide-band gap donor copolymer and (6,6)-phenyl-C₇₁-butyric acid methyl ester (PC₇₁BM) as an acceptor. Silver nanorods (Ag-NRs), synthesized by precipitation method, were embedded in the active layer of the solar cell. The device fabricated with 1 wt % Ag-NRs in the active layer showed a 26% improvement in power conversion efficiency (PCE) when exposed to 100 mW/cm² simulated solar illumination. The role of Ag-NRs in the performance improvement of the OSCs was analyzed systematically using morphological, electrical, and optical characterization methods. The light trapping and exciton generation were improved due to the localized surface plasmon resonance (LSPR) activated in Ag-NRs in the form of longitudinal and transverse modes. The photoactive layers (PIDTT-BTz:PC₇₁BM) with the incorporation of 0.5 and 1 wt % Ag-NR showed increased absorption, while the absorption with 1.5 wt % Ag-NRs appeared to be reduced in the wavelength range from 400 to 580 nm. Ag-NRs play a favorable role in exciton photogeneration and dissociation due to the two LSPR modes generated by the Ag-NRs. In the optimized device, the short-circuit current density (J_SC) increased from 11.92 to 14.25 mA/cm², resulting in an increase in the PCE from 3.94 to 4.93%, which is attributed to the improved light-trapping by LSPR using Ag-NRs.