A nanostructured Al-doped ZnO as an ultra-sensitive room-temperature ammonia gas sensor

Novel chemi-resistive gas sensors with strong detection capabilities operating at room temperature are desirable owing to their extended cycle life, high stability, and low power consumption. The current study focuses on detecting NH₃ at room temperature using lower gas concentrations. The co-precipitation technique was employed to produce pure and Al-doped ZnO nanoparticles, which were calcined at 300 °C for three hours. The effect of aluminium (Al) doping on the structural, morphological, optical, and gas-sensing abilities was investigated and reported. The presence of aluminium was confirmed by XRD, EDX, and FTIR spectroscopy. Additionally, to assess the various characteristics of Al-doped ZnO nanoparticles, scanning electron microscopy (SEM), ultraviolet-visible diffuse reflectance spectroscopy (UV-DRS), atomic force microscopy (AFM), and Brunauer-Emmett-Teller (BET) techniques were used. The crystallite size increased from 14.82 to 17.49 nm in the XRD analysis; the SEM pictures showed a flower-like morphology; and the energy gap decreased from 3.240 to 3.210 eV when Al doping was raised from 1 wt% to 4 wt%. AFM studies revealed topographical information with significant roughness in the range of 230-43 nm. BET analysis showed a mesoporous nature with surface areas varying from 25.274 to 14.755 m²/g and pore diameters ranging from 8.34 to 7.00 nm. The sensing capacities of pure and Al-doped ZnO nanoparticles towards methanol (CH₃OH), toluene (C₇H₈), ethanol (C₂H₅OH), and ammonia (NH₃) were investigated at room temperature. The one-wt% Al-doped ZnO sensor demonstrated an ultrafast response and recovery times at one ppm compared to other AZO-based sensors towards NH₃.