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Multimode Stimuli-Responsive Room-Temperature Phosphorescence Achieved by Doping Butterfly-like Fluorogens into
Zhaozhi Zhang1, Qijing Wang1, Xinyi Zhang1
1Key Laboratory for Advanced Materials, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Joint International Research Laboratory for Precision Chemistry and Molecular Engineering, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai 200237, China.
Researchers developed a simple method to create organic materials that emit light in response to multiple stimuli. These materials offer advanced applications in anticounterfeiting and information encryption.
Area of Science:
- Materials Science
- Organic Chemistry
- Photophysics
Background:
- Stimuli-responsive organic materials with room-temperature phosphorescence (RTP) are highly sought after but often require complex synthesis.
- Existing materials typically exhibit only single-mode switching behavior.
Purpose of the Study:
- To develop efficient RTP systems with multi-stimuli responsiveness using a facile host-guest-doped strategy.
- To achieve tunable photophysical properties without intricate molecular design.
Main Methods:
- Employing a host-guest-doped strategy with butterfly-like guests (N,N'-diphenyl-dihydrodibenzo[a,c]phenazines, DPACs) doped into small-molecular hosts.
- Investigating the role of host crystallinity in RTP efficiency through systematic mechanistic studies and control experiments.
Main Results:
- Successfully constructed efficient RTP systems with tunable photophysical properties.
- Demonstrated multi-stimuli responsiveness, including switching between fluorescence and phosphorescence, and continuous color changes in fluorescence.
- Unveiled the critical role of host crystallinity in achieving efficient RTP.
Conclusions:
- The host-guest-doped strategy provides a versatile route to efficient, multi-stimuli-responsive organic RTP materials.
- These materials enable advanced applications such as dynamic anticounterfeiting and multilevel information encryption.
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