A Molecular Adsorption Concept for Increasing Energy Density of Hybrid Supercapacitors

In this report, we demonstrate that high-capacity hybrid supercapacitors can be realized by utilizing iron azaphthalocyanine (FeAzPc-4N) adsorbed activated carbons (ACs) as an electrode due to the combination of the electric double layer of activated carbon surfaces and redox reactions of FeAzPc-4N molecules. By increasing the mixing ratio of FeAzPc-4N with ACs, a maximum capacity of 907 F/g_AC is achieved, also enabling rapid charging and discharging at 20 A/g. The revelation of the capacitor electrode's durability through 20 000 cycles of charging and discharging is realized, and the capacitor cell had sufficient output power to illuminate LEDs. This concept illustrates the potential for enhancing capacitor performance by immobilizing redox-active species.