Development of superhydrophobic and superoleophilic CNT and BNNT coated copper meshes for oil/water separation

In this research, chemical vapor deposition (CVD) method was used to synthesize boron nitride nanotube (BNNT) powder. This method involves heating multi-walled carbon nanotube (MWCNT) and boric acid in the presence of ammonia gas up to 1000 °C. Then MWCNT and synthetic BNNT were coated on the copper mesh via dip-coating method separately to prepare nano-structured membranes for efficient oil/water separation. Various analyzes were performed to identify the synthetic BNNT properties (X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET), field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS) and prepared coated membranes (FESEM, atomic force microscopy (AFM), water contact angle (WCA), oil contact angle (OCA) and oil/water separation process). Water and oil contact angle analyzes showed the super-oleophilic properties of both membranes with the underwater OCA of about 128°. For the separation process, a dead-end filtration setup was used, and free oil water mixture and o/w emulsion were prepared. So, in the separation process water was retained and decalin passed through both prepared membranes. The flux of CNT coated membrane was about 458 L m² h^-1, while this amount was 1834 L m² h^-1 for BNNT coated membrane and 99% separation efficiency was achieved by both of them. This four-fold increase in flux is due to the fact that the inner diameter of boron nitride nanotubes synthesized is four times larger than the inner diameter of MWCNT.