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Coordination-induced reductive elimination from a titanium(IV) complex.

Paul Fritsche1, Lucia Geyer1, Corinna Czernetzki1

  • 1Julius-Maximilians-Universität Würzburg, Institut für Anorganische Chemie, Am Hubland, 97074 Würzburg, Germany. gabriele.hierlmeier@uni-wuerzburg.de.

Chemical Communications (Cambridge, England)
|July 24, 2024
PubMed
Summary

Titanium dibenzyl complexes with diamidopyridine ligands form titanacyclopentadienes when reacting with alkynes. This coordination-induced C-C reductive elimination reveals a novel radical mechanism for titanium-mediated carbon-carbon bond formation.

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