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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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Synthesis and application of well-defined [Ph4P]+[Cu(CF2CF3)2]- complex as a versatile pentafluoroethylating reagent

Tao Dong1, Qilong Shen2, Gavin Chit Tsui1,3

  • 1Department of Chemistry, The Chinese University of Hong Kong Shatin, New Territories Hong Kong SAR China gctsui@cuhk.edu.hk.

Chemical Science
|July 26, 2024
PubMed
Summary

A novel organocuprate reagent enables efficient pentafluoroethylation across various organic substrates. This single reagent facilitates the formation of diverse carbon-CF2CF3 bonds, simplifying synthetic pathways.

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