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Updated: Jun 18, 2025
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Published on: August 2, 2012
Combining Ti4(embonate)6 anionic cages and π-conjugated coordination cations for highly effective optical limiting
Yuan Yuan1,2, Dong-Hui Zhang1,2, Qiao-Hong Li2
1College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, P. R. China. csm@fzu.edu.cn.
Abstract:
The integration of anionic Ti4L6 (L = embonate) cages and π-conjugated coordination cations into ordered structures can produce high-performance nonlinear optical (NLO) materials. More specifically, by employing Ti4L6 cages for assembly with mixed N,N-chelated and P,P-chelated type conjugated organic ligands and Ag+ ions, three cage-based structures have been synthesized and structurally characterized. Among them, an ion pair structure with strong π-π accumulation exhibits a significant third-order NLO response, and an excellent optical limiting effect has been experimentally verified. This work provides a promising material for NLO applications.
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