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Related Concept Videos

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Related Experiment Video

Updated: Jun 18, 2025

Direct Imaging of Laser-driven Ultrafast Molecular Rotation
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Ultrafast Picometer-Resolved Molecular Structure Imaging by Laser-Induced High-Order Harmonics.

Lixin He1,2, C H Yuen3, Yanqing He1

  • 1Wuhan National Laboratory for Optoelectronics and School of Physics, <a href="https://ror.org/00p991c53">Huazhong University of Science and Technology</a>, Wuhan 430074, China.

Physical Review Letters
|July 29, 2024
PubMed
Summary
This summary is machine-generated.

High-harmonic structure imaging (HHSI) uses intense lasers to visualize molecular changes in attoseconds. This breakthrough method achieves unprecedented spatiotemporal resolution for ultrafast molecular dynamics.

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Area of Science:

  • Ultrafast optical science
  • Physical chemistry
  • Molecular imaging

Background:

  • Real-time molecular transformation visualization is crucial but challenging.
  • Current methods like X-ray and electron diffraction lack sufficient temporal resolution (hundreds of femtoseconds).
  • Few-femtosecond temporal resolution is needed to probe ultrafast molecular dynamics.

Purpose of the Study:

  • To develop a method for imaging molecular transformations with attosecond temporal resolution.
  • To achieve few-picometer spatial resolution for detailed molecular structure analysis.
  • To demonstrate the capability of high-harmonic structure imaging (HHSI) for ultrafast molecular dynamics.

Main Methods:

  • Generating high-order harmonics from intense femtosecond lasers.
  • Exploiting the dependence of molecular recombination dipole moment on molecular geometry.
  • Applying HHSI to monitor structural rearrangements in NH3, ND3, and N2.

Main Results:

  • Achieved few-ten-attosecond temporal resolution and few-picometer spatial resolution.
  • Successfully monitored structural rearrangement in NH3, ND3, and N2 within femtoseconds.
  • Demonstrated the effectiveness of HHSI for ultrafast molecular dynamics.

Conclusions:

  • HHSI provides unprecedented spatiotemporal resolution for molecular dynamics.
  • This technique can resolve molecular structural changes in real-time.
  • HHSI holds potential for future studies of photochemical reactions.