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Heat Flow Estimation in Polymer Films during Orientational Drawing at the Local Heater
Liubov Myasnikova1, Yuri Kurakin2, Vladimir Hilarov1
1Laboratory of Physics of Strength, Ioffe Institute, Politekhnicheskaya 26, 194021 St. Petersburg, Russia.
Polymers
|August 29, 2024
Summary
Investigating polymer film drawing with local heaters revealed that uneven heating causes significant strength differences. Thinner films (<50 μm) ensure uniform temperature distribution for optimal fiber properties.
Area of Science:
- Materials Science
- Polymer Physics
- Mechanical Engineering
Background:
- Polymer film orientational drawing with local heaters is crucial for producing high-strength fibers.
- A key challenge is the discrepancy between theoretical strength predictions and actual fiber strength.
- This disparity is linked to temperature gradients across the film during localized heating.
Purpose of the Study:
- To investigate the impact of unilateral heating on polymer film drawing.
- To analyze the relationship between temperature differences and plastic deformation rates.
- To determine optimal processing parameters for enhanced polymer fiber strength.
Main Methods:
- Numerical calculation of heat conduction and temperature distribution in polymer films.
- Analysis of temperature gradients across film thickness and width during drawing.
- Correlation of temperature homogeneity with film thickness and drawing speed.
Main Results:
- A small temperature difference (1°C) between film surfaces significantly alters plastic deformation rates.
- Tensile stress concentrates on the colder side, potentially generating defects and microcracks.
- Homogeneous temperature distribution, crucial for fibrillar structure transformation, is achieved only for films <50 μm thick.
Conclusions:
- Unilateral heating in local heater drawing processes leads to non-uniform deformation and defects.
- Film thickness is a critical parameter, with <50 μm optimal for uniform temperature distribution.
- This research provides a scientific basis for optimizing drawing speed and film thickness for high-performance polymer filaments like UHMWPE.
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