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We found a unique way to partition thermodynamic quantities in open quantum systems using Hilbert space. This method ensures entropy remains consistent and clarifies how quantum work is distributed, even nonlocally.

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Area of Science:

  • Thermodynamics
  • Quantum Mechanics
  • Statistical Physics

Background:

  • Partitioning thermodynamic quantities in open quantum systems is crucial.
  • Defining entropy, work, and internal energy consistently between system and environment remains challenging.

Purpose of the Study:

  • To identify a robust method for partitioning thermodynamic quantities in open quantum systems.
  • To resolve ambiguities in defining entropy and work in quantum thermodynamics.
  • To establish path independence for system state functions.

Main Methods:

  • Hilbert space partitioning for system-environment coupling.
  • Derivation of a quantum work sum rule.
  • Analysis of thermodynamic quantities in a driven resonant level model.

Main Results:

  • Entropy is nonsingular only under a Hilbert space partition (50/50 system-environment coupling).
  • Quantum work exhibits nontrivial partitioning, requiring a nonlocal work sum rule.
  • State functions become path independent when nonlocal quantum work is included.

Conclusions:

  • A Hilbert space partition provides a consistent framework for quantum thermodynamics.
  • The nonlocal nature of quantum work is essential for defining thermodynamic state functions.
  • The findings offer a new perspective on energy and entropy flow in quantum systems.