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Updated: Jun 13, 2025

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Structural dynamics and optimal transport of an active polymer
Hamidreza Khalilian1, Fernando Peruani2, Jalal Sarabadani3
1School of Nano sciences, Institute for Research in Fundamental Sciences (IPM), 19395-5531, Tehran, Iran. khalilian@ipm.ir.
Active polymers transition between spiral and non-spiral states, mimicking run-and-tumble motion. An optimal self-propelling force maximizes polymer diffusion, revealing key dynamics for active matter.
Area of Science:
- Soft Matter Physics
- Polymer Physics
- Active Matter
Background:
- Active semi-flexible polymers exhibit complex behaviors, including spontaneous shape transitions.
- Understanding these dynamics is crucial for fields ranging from biophysics to materials science.
Purpose of the Study:
- To investigate the configuration transitions of active semi-flexible polymers.
- To characterize the dynamics governing these transitions and relate them to known motion models.
- To identify conditions that optimize polymer diffusion.
Main Methods:
- Theoretical analysis of configuration transitions.
- Modeling polymer dynamics using a subcritical pitchfork bifurcation.
- Comparison of polymer motion to run-and-tumble dynamics.
Main Results:
- The polymer's configuration dynamics are fully described by a subcritical pitchfork bifurcation.
- The observed motion is consistent with run-and-tumble-like dynamics.
- An optimal self-propelling force exists that maximizes the diffusion coefficient.
Conclusions:
- Active semi-flexible polymers exhibit predictable transitions between spiral and non-spiral states.
- The run-and-tumble model effectively describes the polymer's motion.
- Optimizing self-propelling forces is key to controlling polymer diffusion and activity.
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