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Published on: March 24, 2018
Crystal structure of bis-(μ2-5-nona-noylquinolin-8-olato)bis-[aqua-dichlorido-indium(III)]
Betty Fuhrmann1, Eric Meier1, Monika Mazik1
1Technische Universität Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachsen, Germany.
Abstract:
Crystallization of 5-nona-noyl-8-hy-droxy-quinoline in the presence of InCl3 in aceto-nitrile yields a dinuclear InIII complex crystallizing in the space group P. In this complex, [In2(C18H22NO2)2Cl4(H2O)2], each indium ion is sixfold coordinated by two chloride ions, one water mol-ecule and two 8-quinolino-late ions. The crystal of the title complex is composed of two-dimensional supra-molecular aggregates, resulting from the linkage of the Owater-H⋯O=C and Owater-H⋯Cl hydrogen bonds as well as bifurcated Carene-H⋯Cl contacts.
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