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Updated: Jun 10, 2025

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
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Photocatalytic C(sp3)-P and C(sp2)-P Bond Formation via a Phosphorus Radical Cation

Kui Zhang1, Jie Liu1, Yan Li1

  • 1Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, Jiangsu Province Key Laboratory of Green Biomass-Based Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China.

Organic Letters
|October 14, 2024
PubMed

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A bond is formed between two atoms by sharing two electrons. When this bond is broken by supplying sufficient energy, either two electrons can be taken up by one atom forming ions by the cleavage called heterolysis, or the two electrons are shared by two atoms, with one each creating radicals by the cleavage called homolysis.
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A bond can be broken either by heterolytic bond cleavage to form ions or homolytic bond cleavage to yield radicals. A fishhook arrow is used to represent the motion of a single electron in homolytic bond cleavage. There are two main sources from which radicals can be formed:
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