Related Experiment Video
Updated: Jun 10, 2025
Photochemical Oxidative Growth of Iridium Oxide Nanoparticles on CdSe@CdS Nanorods
Published on: February 11, 2016
Oxidative reconstructed Ru-based nanoclusters forming heterostructures with lanthanide oxides for acidic water
Wenxia Xu1, Ziyi Liu1, Yaodong Yu1
1Key Laboratory of Eco-chemical Engineering, Key Laboratory of Optic-electric Sensing and Analytical Chemistry of Life Science, Taishan Scholar Advantage and Characteristic Discipline Team of Eco Chemical Process and Technology, College of Environment and Safety Engineering, College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, PR China.
Abstract:
Achieving rapid anodic oxygen evolution reaction (OER) kinetics and improving the stability of the corresponding ruthenium (Ru)-based catalysts is a current priority for the realisation of industrial water splitting. However, the activity and stability of O2 evolution in electrocatalysis are largely inhibited by the insufficient adsorption of the reactant H2O and too strong adsorption of the intermediate OOH*, as well as by the dissolution of the active site due to excessive oxidation. To solve this challenge, herein, we developed a regulatory strategy combining lanthanide oxides and metal oxidative reconfiguration. The introduction of Eu2O3 effectively promotes the adsorption of H2O, optimizes the adsorption energy of OOH*, and reduces the reaction energy barrier of acidic OER process. And the metal oxidation remodeling process exposed more active sites and prevented the peroxidation process. The optimized Ru/Eu2O3@CNT catalyst showed the highest catalytic activity and stability in acidic OER. Its mass activity was 1219.1 A gRu-1 and the TOF value reached 4.4 s-1 at 1.48 V. Additionally, Ru/Eu2O3@CNT after oxidative reconstruction demonstrates the industrially needed current density of 1.0 A cm-2 at 1.71 V in PEM electrolyser, achieving stability in excess of 200 h.
