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Porosity in Cement Paste01:18

Porosity in Cement Paste

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The porosity of concrete is a measure of the void spaces within its structure. These spaces impact its strength and durability significantly. When water and cement interact, a chemical reaction called hydration creates a semi-solid paste. This paste includes combined water, making up approximately 23% of the cement's dry mass, and gel water, which fills minuscule voids known as gel pores, accounting for about 28% of the cement gel volume.
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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
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In concrete, the pore size distribution significantly influences the material's properties. Capillary pores, markedly larger than gel pores, form a vast network within partially hydrated cement paste, reducing the concrete's strength and increasing its permeability. This heightened permeability leads to a greater risk of damage from environmental factors like freeze-thaw cycles and chemical attacks, with the extent of vulnerability also being tied to the water-to-cement ratio.
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Unless individual gases chemically react with each other, the individual gases in a mixture of gases do not affect each other’s pressure. Each gas in a mixture exerts the same pressure that it would exert if it were present alone in the container. The pressure exerted by each individual gas in a mixture is called its partial pressure.
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Porosity and Absorption of Aggregate01:20

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Aggregates contain pores of varying sizes; while some are completely enclosed within the particles, others open onto the surface, allowing water to penetrate. The porosity of aggregates is a major factor contributing to the overall porosity of concrete, given that aggregates constitute about three-quarters of concrete's volume.
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Related Experiment Video

Updated: Jun 8, 2025

Surface Properties of Synthesized Nanoporous Carbon and Silica Matrices
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Surface Properties of Synthesized Nanoporous Carbon and Silica Matrices

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The Effect of Fractional Composition on the Graphite Matrices' Porosity.

Mariya D Gritskevich1, Alexandra V Gracheva1, Mariya S Filippova1

  • 1Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia.

Materials (Basel, Switzerland)
|November 9, 2024
PubMed
Summary

Researchers developed porous carbon matrices using synthetic graphite and phenolic resin. Optimal conditions were identified for creating graphitized carbon matrices suitable for high-intensity silicon infiltration.

Keywords:
fractional compositionliquid silicon infiltrationphenolic resinporosityporous graphite matricessynthetic graphite

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Area of Science:

  • Materials Science
  • Chemical Engineering

Background:

  • Porous carbon matrices are crucial for advanced material applications.
  • Phenolic resin is a common binder and pore-forming agent in carbon matrix production.

Purpose of the Study:

  • To investigate the structural transformations of phenolic resin during carbonization.
  • To establish relationships between matrix volume density, open porosity, and average pore diameter.
  • To determine optimal conditions for producing graphitized carbon matrices for silicon infiltration.

Main Methods:

  • Mixing synthetic graphite with phenolic resin.
  • Pressing and heat-treating mixtures to form porous matrices.
  • Studying phenolic resin structural changes up to 900 °C in oxygen and inert atmospheres.
  • Investigating carbonization patterns and pore system amorphization.

Main Results:

  • Identified regularities in matrix volume density changes with porosity and pore diameter.
  • Determined that ≤20% phenolic resin with specific graphite fractions yields desired matrix properties.
  • Achieved graphitized carbon matrices with ~1 g/cm³ density and ≥50% open porosity.

Conclusions:

  • The study provides a method for creating tailored porous carbon matrices.
  • The optimized matrices facilitate high-intensity and complete bulk silicon infiltration.
  • This research contributes to the development of advanced composite materials.