Self-Supported Porous Carbon Monoliths for Electrocatalytic Hydrogen Evolution in Alkaline Freshwater and Seawater

Developing efficient catalysts for seawater electrolysis hydrogen evolution reaction (HER) is crucial for producing green hydrogen. Carbonized wood (CW), a porous carbon monolith, is a promising self-supporting electrocatalytic electrode owing to its environmentally friendly, sustainable, and hierarchically porous properties. However, the impact of different tree species on the hydrogen evolution performance remains unclear. In this study, various types of CWs, including carbonized poplar (PoCW), carbonized balsa (BaCW), carbonized fir (FiCW), and carbonized pine (PiCW), have been selected to investigate their electrocatalytic performance in hydrogen evolution. Among these, the PoCW exhibits superior electrocatalytic HER performance compared to the other CWs, attributed to its electrochemically active surface area, resistance, and the content of oxygen-containing functional groups. PoCW demonstrates a low overpotential of 284 mV and 356 mV at 10 mA cm^-2 in alkaline freshwater and seawater, respectively. Moreover, PoCW shows long-term durability for 100 h in both alkaline freshwater and seawater. This work guides the selection of wood-based carbon monoliths and demonstrates that metal-free, CW-based self-supporting electrodes hold great potential for electrocatalytic hydrogen evolution in both freshwater and seawater.