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Updated: Jun 5, 2025

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
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Direct synthesis of PtNi coated with Ni3B for efficient electrochemical hydrogen evolution from seawater

Xiong Yang1, Yu-Xuan Xiao2, Fei Yu1

  • 1State Key Laboratory of Silicate Materials for Architectures & State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & School of Chemistry, Chemical Engineering and Life Sciences & Laoshan Laboratory & School of Materials Science and Engineering & International School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, 430070, China. xyyang@whut.edu.cn.

Chemical Communications (Cambridge, England)
|December 12, 2024
PubMed

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Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation...
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