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A versatile reusable polymer-based sensor for aluminum analysis in various food matrices
Soner Çubuk1, Pelin Kaplan1, Belma Gjergjizi Nallbani2
1Department of Chemistry, Faculty of Science, Marmara University, 34722 Istanbul, Turkey.
A novel polymer-based optical sensor was developed for sensitive aluminum determination in food samples. This UV-polymerizable sensor offers rapid, selective detection with a low limit, enhancing food safety analysis.
Area of Science:
- Analytical Chemistry
- Materials Science
- Food Science
Background:
- Accurate aluminum determination is crucial for food safety and quality control.
- Existing methods for aluminum detection can be complex and time-consuming.
- Development of rapid, selective, and sensitive sensors is needed for routine analysis.
Purpose of the Study:
- To develop and validate a polymer-based optical sensor for aluminum determination.
- To assess the sensor's performance in complex food matrices like yogurt, soybean flour, and meat.
- To characterize key analytical parameters including sensitivity, selectivity, and detection limits.
Main Methods:
- Fabrication of a UV-polymerizable polymer-based optical sensor.
- Optimization of sensor parameters: operating range, pH, reaction time, and selectivity.
- Spectroscopic analysis using fluorescence excitation (322 nm) and emission (356 nm) wavelengths.
Main Results:
- The developed sensor demonstrated high sensitivity and selectivity for aluminum.
- Optimal performance was achieved at pH 3.0 with a rapid reaction time of 20-40 seconds.
- A linear working range of 7.41 × 10⁻⁹–1.11 × 10⁻⁷ mol L⁻¹ and a detection limit of 2.09 × 10⁻⁹ mol L⁻¹ were established.
Conclusions:
- The polymer-based optical sensor provides a reliable and efficient method for aluminum quantification in diverse food products.
- The sensor's characteristics make it suitable for rapid screening and quality control applications in the food industry.
- This approach offers a promising alternative to conventional analytical techniques for trace metal analysis in food.
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