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Mutual suppression of Mn3O4 and SiO in an innovative anode design for enhanced cycling stability

Miao Li1, Quan Ouyang1, Kai Yao1

  • 1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China. lipingli@jlu.edu.cn.

Chemical Communications (Cambridge, England)
|January 14, 2025
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Activated manganese(IV) oxide can selectively oxidize allylic and benzylic alcohols via a radical intermediate mechanism. Primary allylic alcohols are oxidized to aldehydes, while secondary allylic alcohols yield ketones. The redox reaction of potassium permanganate with an Mn(II) salt such as manganese sulfate (under either alkaline or acidic conditions), followed by thorough drying, yields the oxidizing agent: activated MnO2. While MnO2 is insoluble in the solvents used for the reaction, the...
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