Cross-diffusion waves by cellular automata modeling: Pattern formation in porous media

Porous earth materials exhibit large-scale deformation patterns, such as deformation bands, which emerge from complex small-scale interactions. This paper introduces a cross-diffusion framework designed to capture these multiscale, multiphysics phenomena, inspired by the study of multi-species chemical systems. A microphysics-enriched continuum approach is developed to accurately predict the formation and evolution of these patterns. Utilizing a cellular automata algorithm for discretizing the porous network structure, the proposed framework achieves substantial computational efficiency in simulating the pattern formation process. This study focuses particularly on a dynamic regime termed "cross-diffusion wave," an instability in porous media where cross-diffusion plays a significant role-a phenomenon experimentally observed in materials like dry snow. The findings demonstrate that external thermodynamic forces can initiate pattern formation in cross-coupled dynamic systems, with the propagation speed of deformation bands primarily governed by cross-diffusion and a specific cross-reaction coefficient. Owing to the universality of thermodynamic force-flux relationships, this study sheds light on a generic framework for pattern formation in cross-coupled multi-constituent reactive systems.