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Through-space conjugation driven luminescence enhancement in crystalline butterfly architectures
Suvarna Sujilkumar1, Avinash Hari2, Mahesh Hariharan1
1School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, Maruthamala P.O., Vithura, Thiruvananthapuram, Kerala 695551, India. mahesh@iisertvm.ac.in.
Abstract:
Through-space conjugation in organic chromophores offers significant potential for developing highly efficient luminescent materials. Herein, we investigate the luminescencent properties of crystalline tetra-naphthalene connected dihydropentacene isomers, 1-NP and 2-NP, using both experimental and theoretical approaches, establishing the presence of through-space conjugation mediated luminescence enhancement.
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