A novel type of planar reference electrodes based on ionic liquids

Although electrochemical sensors gained a lot of popularity through recent years, there is very little research on sensors with IL-based reference electrodes. This type of reference electrodes might be the ultimate solution for problem of RE miniaturization. In this paper a novel type of printed reference electrodes based on ionic liquids are presented. The potential stability of electrodes with membranes containing two new ILs with promising properties, namely 1-ethyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate (EMIM⁺FAP^-) and 1-(2-methoxyethyl)-1-methylpyrrolidin-1-ium tris(pentafluoroethyl)trifluorophosphate (PYR(2o1,1)⁺FAP^-), was investigated. Reference membranes were implemented in classic electrodes with internal electrolyte, as well as deposited on planar transducers with electrodes fabricated using screen printing or aerosol jet printing. Membranes were deposited via drop-casting or by using aerosol jet printer, to form fully printed reference electrodes. It was found that while both tested ionic liquids performed similarly, the use of (PYR(2o1,1)⁺FAP^-) resulted in better potential stability. Planar IL-based electrode was finally used as a reference electrode in a simple pH sensor, enabling the detection of pH changes.