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Updated: May 25, 2025
Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
Chemical CO2 fixation by a heterogenised Zn(ii)-hydrazone complex
Neda Heydari1, Rahman Bikas1, Tadeusz Lis2
1Department of Chemistry, Faculty of Science, Imam Khomeini International University Qazvin 34148-96818 Iran bikas@sci.ikiu.ac.ir bikas_r@yahoo.com.
Abstract:
A new Zn(ii) coordination compound, [Zn(HL)(OAc)2] (1), with ONN-donor hydrazone ligand (HL = (E)-4-amino-N'-(1-(pyridin-2-yl)ethylidene)benzohydrazide) was synthesized and structurally characterized by using spectroscopic techniques and X-ray analysis. These analyses indicated that the Zn(ii) ion in the resulting coordination compound is five coordinated and the compound has a free amine functionality on the phenyl ring. Thus, [Zn(HL)(OAc)2] (1) was immobilized on the surface of propionylchloride functionalized silica gel through an amidification process via the reaction of the aniline part of compound 1 and the acyl chloride group of the support. The synthesized heterogeneous catalyst, Si-[Zn(HL)(OAc)2], was characterized by several analytical methods and the results confirmed the successful support of 1 on the surface of the support. Si-[Zn(HL)(OAc)2] was used in a chemical CO2 fixation reaction and styrene epoxide was used as a model substrate to investigate the catalytic performance of the supported Zn(ii) catalyst. Si-[Zn(HL)(OAc)2] can efficiently catalyze the formation of cyclic carbonate from the reaction of epoxide and CO2 in the presence of TBAB as a co-catalyst.
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