Fundamentals, Advances and Perspectives in Designing Eutectic Electrolytes for Zinc-Ion Secondary Batteries

Zinc-ion secondary batteries have been competitive candidates since the "post-lithium-ion" era for grid-scale energy storage, owing to their plausible security, high theoretical capacity, plentiful resources, and environment friendliness. However, many encumbrances like notorious parasitic reactions and Zn dendrite growth hinder the development of zinc-ion secondary batteries remarkably. Faced with these challenges, eutectic electrolytes have aroused notable attention by virtue of feasible synthesis and high tunability. This review discusses the definition and advanced functionalities of eutectic electrolytes in detail and divides them into nonaqueous, aqueous, and solid-state eutectic electrolytes with regard to the state and component of electrolytes. In particular, the corresponding chemistry concerning solvation structure regulation, electric double layer (EDL) structure, solid-electrolyte interface (SEI) and charge/ion transport mechanism is systematically elucidated for a deeper understanding of eutectic electrolytes. Moreover, the remaining limitations and further development of eutectic electrolytes are discussed for advanced electrolyte design and extended applications.