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Raman spectroscopy for forensic pen ink investigation: a review
Rosane R Souza1,2, Lucas M Duarte1, Glaucio B Ferreira1
1Universidade Federal Fluminense, Instituto de Química, Campus do Valonguinho, 24020-150, Niterói, RJ, Brazil. glauciobf@id.uff.br.
Raman spectroscopy (RS) offers a powerful, non-destructive method for analyzing pen inks in questioned documents, aiding forensic investigations and fraud detection. This technique shows promise for trace evidence analysis and document dating.
Area of Science:
- Forensic Science
- Analytical Chemistry
- Spectroscopy
Background:
- Raman spectroscopy (RS) has advanced significantly, offering advantages in diverse fields like forensics.
- Non-destructive analysis is crucial for preserving criminal evidence in forensic investigations.
- Pen ink characterization is vital for questioned documents, trace evidence, and dating investigations.
Purpose of the Study:
- To review the evolution of Raman spectroscopy techniques for pen ink identification.
- To explore the application of RS in characterizing document fraud.
- To compare RS with traditional analytical methods for ink analysis.
Main Methods:
- Review of literature on Raman spectroscopy techniques for ink analysis.
- Comparison of RS with conventional methods (e.g., microscopy, chromatography).
- Analysis of data to guide the selection of appropriate ink analysis methodologies.
Main Results:
- Raman spectroscopy demonstrates significant potential for identifying and characterizing pen inks.
- RS is effective for detecting alterations and potential fraud in documents.
- The review provides comparative data to aid in choosing optimal ink analysis techniques.
Conclusions:
- Raman spectroscopy is a valuable non-destructive tool for forensic document examination.
- RS offers advantages over traditional methods for pen ink analysis and fraud detection.
- This review assists forensic scientists in selecting the most suitable RS methodology for ink analysis.
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