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Updated: May 21, 2025
08:12
Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
Published on: December 16, 2022
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Enzymatic polymerization: Recent advances toward sustainable polymer synthesis
Bo Xia1, Honghao Chen1, Juntao Wang1
1Jiyang College of Zhejiang A&F University, Zhuji 311800, China.
Biotechnology Advances
|March 21, 2025
Summary
Enzymatic polymerization offers a sustainable route to biodegradable polymers, tackling environmental issues. This review details key enzymes and multi-enzyme systems driving innovation in eco-friendly material synthesis.
Area of Science:
- Polymer Chemistry
- Biotechnology
- Green Chemistry
Background:
- Conventional petroleum-based polymers pose significant environmental challenges.
- Biodegradable and biocompatible polymers are crucial for sustainable material development.
- Enzymatic polymerization presents a promising eco-friendly alternative.
Purpose of the Study:
- To review recent advancements (past five years) in enzymatic polymerization.
- To systematically classify enzymatic polymerization mechanisms and highlight key enzymes.
- To explore strategies for polymer architecture customization and industrial applications.
Main Methods:
- Comprehensive literature review focusing on enzymatic polymerization.
- Analysis of six pivotal enzymes: lipase, horseradish peroxidase, laccase, glucose oxidase, glucosyltransferase, and phosphorylase.
- Examination of synergistic multi-enzymatic systems and cascade catalysis.
Main Results:
- Identification of key enzymes and their roles in polymerization.
- Classification of enzymatic polymerization mechanisms based on substrate specificity, efficiency, and product diversity.
- Integration of enzyme engineering and green chemistry principles.
Conclusions:
- Enzymatic polymerization offers diverse pathways to sustainable polymers.
- Challenges in scaling enzymatic processes and opportunities for industrial application are identified.
- Interdisciplinary innovation is vital for advancing enzymatic methods in line with circular economy principles.
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