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Femtosecond Laser Manipulation of Multistage Phase Switching in Two-Dimensional In2Se3 Visualized via an In Situ

Junqing Guo1, Lifu Zhang2, Meiling Zhang1

  • 1Ultrafast Electron Microscopy Laboratory, The MOE Key Laboratory of Weak-Light Nonlinear Photonics, School of Physics, Nankai University, Tianjin 300071, China.

ACS Nano
|March 27, 2025
PubMed
Summary

Femtosecond lasers enable precise, rapid control over multiphase transitions in indium selenide (In2Se3) thin flakes. This breakthrough offers new possibilities for advanced electronic memory devices.

Keywords:
In2Se3ferroelectric materialsin situ TEMphase transitionvan der Waals materials

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Nanotechnology

Background:

  • Phase transitions are crucial for material properties and device applications.
  • Two-dimensional (2D) indium selenide (In2Se3) exhibits complex phase switching and ferroelectric properties, but lacks precise control methods.
  • Existing challenges hinder the practical application of In2Se3 in devices.

Purpose of the Study:

  • To investigate the use of femtosecond (fs) lasers for precise multiphase transition control in 2D In2Se3.
  • To explore the dynamics of phase switching and associated property changes.
  • To provide foundational insights for optimizing memory devices.

Main Methods:

  • In situ transmission electron microscopy (TEM) with fs laser irradiation.
  • Controlled manipulation of laser fluence to induce phase transitions.
  • First-principles calculations to verify transition pathways and electronic structures.

Main Results:

  • Achieved controllable, fast phase switching between four phases of 2D In2Se3 using fs laser fluence.
  • Demonstrated reversible switching between antiferroelectric and paraelectric phases at room temperature.
  • Observed rapid changes in electrical conductivity linked to domain structure evolution and electronic band structure variations.

Conclusions:

  • Femtosecond laser irradiation is an effective tool for precise and rapid multiphase control in In2Se3.
  • Understanding the relationship between phase transitions, electronic structure, and conductivity is key for device applications.
  • This research lays the groundwork for developing advanced memory devices based on In2Se3.