Near-Infrared Ytterbium Complexes Based on Polycyclic Aromatic Dicarboxylate Ligands and the Solution-Processed NIR...

Since the O-H and N-H oscillators of solvent molecules attached to ytterbium ion (Yb³⁺) and C-H oscillators existing in the inner coordination sphere of Yb³⁺ would quench the excited energy of Yb(III), which leads to low quantum yields (QYs) of Yb(III) complexes, we aimed to design a ligand that could block solvent molecules and C-H oscillators out of the first coordination sphere of Yb³⁺. Herein, a series of novel polycyclic aromatic dicarboxylate ligands are designed and synthesized to effectively protect Yb³⁺ from solvent molecules and efficiently sensitize Yb³⁺ luminescence, while the cost and sophistication of the synthesis are satisfactory. Therein, [Yb(MO-DPyPDA)₂](DIEA) exhibited a considerable QY of 5.20% and a long luminescent lifetime of 102 μs in CD₃OD. The single-crystal structure demonstrates that there are no solvent molecules and C-H oscillators existing in the inner coordination sphere of Yb³⁺, which is conducive to alleviating the quenching effect. Meanwhile, we also carried out experiments to verify that it was thermodynamically feasible for ligands to sensitize the luminescence of center ion through internal redox processes. Moreover, several groups of near-infrared organic light-emitting diodes based on [Yb(DTFM-DPyPDA)₂](DIEA) were fabricated based on the solution-processing method, and the highest irradiance of 110,284 μW/m² was realized by optimizing the device structure.