Next-Generation Edible Packaging: Development of Water-Soluble, Oil-Resistant, and Antioxidant-Loaded Pouches for Use...

The development of sustainable biodegradable packaging materials is essential for enhancing food quality and shelf life while reducing plastic waste. This study explored polymer-based monolayer, composite, and bilayer films to produce water-soluble, oil-proof pouches. Single-serving seasoning oil pouches were prepared from bilayer films with polyvinyl alcohol (PVA) as the inner and sodium alginate (SA) as the outer layer. The PVA/SA films exhibited excellent UV protection, low oil permeability (0.18 × 10^-6 g·mm/mm²·day), hydrophilic surface (water contact angle < 90°), and rapid solubility in hot water (87 ± 2 °C). Incorporating curcumin, a natural antioxidant, into PVA/SA films (Cur-PVA/SA) improved thermal stability, reduced light transmittance, and decreased water vapor permeability (0.28 × 10^-10 g/m·Pa·s). Curcumin release followed a biphasic diffusion model, with 94.8% released at 96 h (diffusion coefficient: 1.30 × 10^-11 m²/s), ensuring prolonged antioxidant activity. The Cur-PVA/SA pouches delayed lipid oxidation more effectively, with peroxide values of 6.48 and 10.35 meq/kg after 45 days at 35 °C, respectively. The Q₁₀ model, which is commonly used to predict the shelf life of oils based on temperature-dependent oxidation rates, estimated that the oil packaged in Cur-PVA/SA pouches would remain stable for 12 months at 23 °C. This represents a 37% longer shelf life compared to oil packaged in PVA/SA pouches without curcumin. Cur-PVA/SA pouches also reduced noodle moisture migration, limiting weight loss to 2.73% over 14 days compared to 5.80% in controls. These findings highlight their potential as eco-friendly active packaging solutions.