Continuous photocatalytic C-C coupling achieved using palladium anchored to a covalent organic framework
Chao Ma1, Zhe Wu1, Yi-Tong Hou1
1Institute for New Energy Materials and Low Carbon Technologies, School of Material Science & Engineering, Tianjin University of Technology, Tianjin 300384, China. guosong@email.tjut.edu.cn.
Abstract:
We firstly reported a single-atom palladium photocatalyst, Pd-Ace-COF, for a continuous C-C coupling reaction. Under visible light irradiation, Pd-Ace-COF efficiently drives C-C coupling to form biphenyl with a >99% yield. Impressively, Pd-Ace-COF exhibits good stability and high activity in the continuous-flow reactor, highlighting its great potential for practical applications.
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