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Molecules with Multiple Chiral Centers

Molecules with Multiple Chiral Centers

Molecules that possess multiple chiral centers can afford a large number of stereoisomers. For instance, while some molecules like 2-butanol have one chiral center, defined as a tetrahedral carbon atom with four different substituents attached, several molecules like butane-2,3-diol have multiple chiral centers. A simple formula to predict the number of stereoisomers possible for a molecule with n chiral centers is 2n. However, there can be a lower number where some of the stereoisomers are...

Stereoisomerism

Stereoisomerism

Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...

Chirality

Chirality

Chirality is a term that describes the lack of mirror symmetry in an object. In other words, chiral objects cannot be superposed on their mirror images. For example, our feet are chiral, as the mirror image of the left foot, the right foot, cannot be superposed on the left foot.
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...

Properties of Enantiomers and Optical Activity

Properties of Enantiomers and Optical Activity

It is essential to understand the difference between chiral and achiral interactions and the implications thereof in optical activity and their applications. Just as our feet, which are chiral, interact uniquely with chiral objects, such as a pair of shoes, but identically with achiral socks, enantiomers of a molecule exhibit different properties only when they interact with other chiral media. An example of a significant implication from this facet is the phenomenon known as optical activity,...

Prochirality

Prochirality

The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...

Thermal Electrocyclic Reactions: Stereochemistry

Thermal Electrocyclic Reactions: Stereochemistry

The stereochemistry of electrocyclic reactions is strongly influenced by the orbital symmetry of the polyene HOMO. Under thermal conditions, the reaction proceeds via the ground-state HOMO.
Selection Rules: Thermal Activation
Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.

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Related Experiment Video

Updated: May 15, 2025

An Electrochemical Cholesteric Liquid Crystalline Device for Quick and Low-Voltage Color Modulation

An Electrochemical Cholesteric Liquid Crystalline Device for Quick and Low-Voltage Color Modulation

Published on: February 27, 2019

Optical Binary Operator Based on Thermally Controllable Chiral Superstructures.

Yi-Heng Zhang¹, Shi-Hui Ding¹, Yi-Ming Wang¹

¹National Laboratory of Solid State Microstructures, Key Laboratory of Intelligent Optical Sensing and Manipulation, College of Engineering and Applied Sciences, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China.

|May 5, 2025

Summary

This summary is machine-generated.

Researchers developed an optical binary operator using chiral nanostructures for light-based computing. This innovation enables complex calculations on data and images, advancing optical informatics.

Keywords:

binary operators geometric phases optical computing self-assembled chiral superstructures thermal response

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Area of Science:

Optics and Photonics
Materials Science
Optical Computing

Background:

Structured optical materials are shifting optical informatics from displaying to computing with light.
Binary operators are essential mathematical functions with applications in Boolean logic.

Purpose of the Study:

To propose and demonstrate an optical binary operator.
To leverage thermally controllable chiral nanostructures for optical computing.
To explore the use of Pancharatnam-Berry phase for enhanced computing functionalities.

Main Methods:

Engineering anisotropic and chiral materials to create thermally controllable nanostructures.
Utilizing the interplay between material properties and light inputs to determine operator output.
Modulating orbital angular momentum and intensity distribution of light for binary operations.

Main Results:

Demonstration of an optical binary operator based on chiral nanostructures.
Successful implementation of binary operations on integers and images.
Achieved a tunable operating spectrum spanning 1600 nm (visible to near-infrared).

Conclusions:

The developed optical binary operator offers new possibilities for soft matter applications.
This technology has potential applications in machine vision and optical artificial intelligence.
The study advances the field of computing with light using structured optical materials.