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Polychlorinated Alkanes in feed from the German market
Jakob Hauns1, Lena Zeug1, Lena Moosmann1
1European Reference Laboratory for halogenated POPs in Feed and Food (EURL POPs), Bissierstr.5, 79114, Freiburg, Germany.
Chemosphere
|May 14, 2025
Summary
Polychlorinated alkanes (PCAs) were detected in German animal and plant feed. Concentrations were higher in animal feed, especially fish meal, and plant-based fats/oils, possibly due to Stockholm Convention enforcement.
Area of Science:
- Environmental Chemistry
- Food Safety Analysis
- Contaminant Monitoring
Background:
- Polychlorinated alkanes (PCAs) are persistent organic pollutants.
- PCAs can accumulate in the food chain, posing risks to animal and human health.
- Understanding PCA levels in animal feed is crucial for food safety.
Purpose of the Study:
- To quantify Polychlorinated alkanes (PCAs) in animal and plant-origin feed samples.
- To compare PCA concentrations between different feed types.
- To investigate potential sources and factors influencing PCA levels in feed.
Main Methods:
- Analysis of 47 feed samples (13 animal, 34 plant) from the southern German market in 2023.
- Gas chromatography-mass spectrometry (GC-MS) or similar techniques were likely employed for PCA quantification.
- Statistical analysis to determine median concentrations and compare feed types.
Main Results:
- Overall median PCA concentration was 10 ng/g wet weight (ww).
- Animal-origin feeds (median 44 ng/g ww) had significantly higher PCA levels than plant-origin feeds (median 8.8 ng/g ww).
- Highest PCA levels were found in plant-based fats/oils and fish meal; lowest in seeds, press cakes, and soy products.
Conclusions:
- PCA contamination varies significantly between feed types, with animal feed showing higher levels.
- Plant-based fats/oils and fish meal represent key matrices for PCA accumulation in feed.
- The observed PCA patterns may reflect the impact of European regulations like the Stockholm Convention.
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