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Updated: Sep 19, 2025
![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Cyclometallated phosphonium ylide-based iridium(III) photocatalysts
Oussama Fayafrou1, Juliette Zanzi1, Carine Duhayon1
1LCC-CNRS, Université de Toulouse, CNRS, UPS, Toulouse, France. olivier.basle@lcc-toulouse.fr.
Abstract:
A novel class of cyclometallated photoactive iridium(III) complexes containing phosphonium ylide ligands has been synthesized and thoroughly characterized. Their photophysical and redox properties have been systematically investigated and employed in photocatalytic applications. Notably, these complexes exhibit high activity in visible-light-mediated EnT and SET processes.
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